100% Stun Chance?

So I noticed that with most of the mace stun threshold reduction passives, heavy strike, and a stun support gem, you can get over 100% stun threshold reduction, which should mean you automatically stun on every hit. Is this as powerful as it sounds?
You can have 100% stun agaist some enemies but some other have resitance so no 100% stun threshold reduction doesnt mean 100% chanse of stun, but for sure you gonna be able to stun most things whit 100% since 100% is a good stun threshold reduction

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